If you want to export emails from Outlook.com to PST, then you can try it with the Advik Outlook.com Backup Tool. It is such a sophisticated approach that allows users to instantly export outlook.com to PST in bulk. You can choose the selective email folders that you wish to export. Also, you can configure an Outlook.com email account with Outlook to easily sync all emails, and with Import Export wizard, export into PST file format.
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